Chemistry Letters p. 1853 - 1856 (1987)
Update date:2022-08-02
Topics:
Ishiguro, Katsuya
Sawaki, Yasuhiko
Iwamura, Hiizu
A novel cycloaddition mechanism involving diazomethane radical cations is proposed for the dimeric olefin formation by the one-electron oxidation of the diazo-compounds.The preference of cis-stilbene formation from phenyldiazomethane is understood by a secondary orbital interaction of phenyl groups on the cycloaddition step.
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