Russian Chemical Bulletin p. 1825 - 1827 (1998)
Update date:2022-08-16
Topics:
Shainyan
Danilevich
Oxidation of aryl vinyl sulfides into aryl vinyl sulfoxides in the ButOOH-Ti(OPri)4-(R, R)-diethyl tartrate system was studied. The process afforded low optical yields (no more than 5%). A model of the oxidation was proposed that allows interpreting the dependence of the reaction enantioselectivity on the structure of a substrate.
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