PALLADIUM(0)-PROMOTED CROSS-COUPLING OF ALLENYLMETAL COMPOUNDS WITH ARYL AND VINYL IODIDES. A NOVEL ROUTE TO ARYL- AND VINYL-SUBSTITUTED ALLENES

DOI: 10.1016/S0022-328X(00)93180-2

Source and publish data:

Journal of Organometallic Chemistry p. 399 - 405 (1982)

Update date:2022-08-16

Topics:

Authors:

Ruitenberg, K.

Kleijn, H.

Meijer, J.

Oostveen, E. A.

Vermeer, P.

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Article abstract of DOI:10.1016/S0022-328X(00)93180-2

The reaction of allenylmetal compounds, RR'C=CHM (I), with aryl and vinyl iodides, R''I, have been studied.With Pd(PPh3)4 as catalyst a highly regioselective formation of allenes, RR'C=C=CHR'' (II), has been observed for M=MgCl, Cu, Cu1/2Li1/2, Ag, Ag1/2L

Full text of DOI:10.1016/S0022-328X(00)93180-2

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