Dimetallation of Phenylacetylene. Selective ortho-Substitution

DOI: 10.1039/c39810000366

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 366 - 367 (1981)

Update date:2022-08-16

Topics:

Authors:

Hommes, Hendrik

Verkruijsse, Hermann D.

Brandsma, Lambert

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39810000366

Reaction of lithium phenylacetylide with the complex BuLi-Bu^tOK in a mixture of tetrahydrofuran and hexane leads to the ortho-metallated phenylacetylide; subsequent addition of methyl iodide, dimethyl disulphide, trimethylchlorosilane, and sele

Full text of DOI:10.1039/c39810000366

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1-PHENYL-2-(TRIMETHYLSILYL)ACETYLENE

Cas No:2170-06-1

R&D Labs maybe for 2170-06-1

Chongqing Werlchem Fine Chemical Co. Ltd

Contact:+86-23-67521957

Address:NO.15,Fortune Road,Yubei District,401121,Chongqing,China
Aecochem Corp.

website:http://www.aecochemical.com

Contact:+86-592 599 8717

Address:No 611 Sishui Road,Huli
Jinan Yijialian Economic and Trade Development Co., Ltd.

Contact:+86 0531-66729596

Address:jinan
Shanghai He Yang International Trading Co., Ltd.

Contact:+86-21-52043598

Address:Room 816, Blag.5, No.58 Huachi Road
AllyChem Co., Ltd., Dalian, China（BBChem）

Contact:+86-411-62313318/62313328

Address:No.5 of Jinbin Road, Jinzhou New District, Dalian City, Liaoning Province, P.R.China

Relevant to this article

Doi:10.1021/ja01011a055
(1968)
Green Catalyst-free Multi-component Synthesis of Aminobenzochromenes in Deep Eutectic Solvents

Doi:10.1080/00304948.2020.1714319
(2020)
Doi:10.1089/107628001300000651
(1930)
Nickel oxide nanoparticles grafted on reduced graphene oxide (rGO/NiO) as efficient photocatalyst for reduction of nitroaromatics under visible light irradiation

Doi:10.1016/j.jphotochem.2016.12.023
(2017)
Kinetics and Mechanism of the Silver(I)-catalyzed Oxidations of Arsenic(III) and Antimony(III) with Peroxodiphosphate in Acetate Buffers

Doi:10.1039/DT9840001873
(1984)
Isocyanate Intermediates. II. Trichloromethyl Chloroformate - A Convenient Reagent for the Preparation of Diisocyanates with Benzene or Furan Rings

Doi:10.1002/prac.19923340218
(1992)

Article Doi