Dimetallation of Phenylacetylene. Selective ortho-Substitution

DOI: 10.1039/c39810000366

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 366 - 367 (1981)

Update date:2022-08-16

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Authors:

Hommes, Hendrik

Verkruijsse, Hermann D.

Brandsma, Lambert

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Article abstract of DOI:10.1039/c39810000366

Reaction of lithium phenylacetylide with the complex BuLi-Bu^tOK in a mixture of tetrahydrofuran and hexane leads to the ortho-metallated phenylacetylide; subsequent addition of methyl iodide, dimethyl disulphide, trimethylchlorosilane, and sele

Full text of DOI:10.1039/c39810000366

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