Inorganic Chemistry p. 3719 - 3721 (1981)
Update date:2022-08-04
Topics:
Boucher, Heather
Sargeson, Alan M.
Sangster, David F.
Sullivan, James C.
Oxidation of [Co(NH3)5(N3)]2+ with hydroxyl radical (k = 1.1 × 109 M-1 s-1) has been observed to yield a surprisingly stable coordinated radical, presumed to be [Co(NH3)5NNNOH·]2+ which decays by a first-order intramolecular redox process (k = 60 ± 10 s-1 at 25°C) to give Co(II), N2, and N2O as products. N2O appears to arise from dimerization of NOH to H2N2O2 which decomposes in acidic solution to N2O and H2O.
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