Journal of Organic Chemistry p. 4432 - 4440 (1980)
Update date:2022-08-29
Topics:
Nakazaki, Masao
Chikamatsu, Hiroaki
Naemura, Koichiro
Asao, Masaaki
The stereochemistry of the isomeric alcohols obtained from microbial reduction (Curvularia lunata and Rhodotorula rubra) of the racemic modification of bicyclic (5,8,23), benzobicyclic (11,14,17), and tricyclic(20) ketones with a wide variation in molecular framework has led to the formulation of a quadrant rule which provides information on the absolute configuration of the substrate ketone.
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