Journal of the American Chemical Society p. 7935 - 7938 (1986)
Update date:2022-08-16
Topics:
Adams, J. Stephen
Burton, Katherine A.
Andrews, B. Kim
Weisman, R. Bruce
Engel, Paul S.
The gas-phase photodissociation of an unsymmetrical azoalkane, 3-(methylazo)-3-methyl-1-butene, was studied with time-resolved coherent anti-Stokes Raman spectroscopy (CARS) to probe for product formation.Appearance kinetics were measured for all three primary photoproducts.The results indicate a two-step dissociation mechanism in which the 1,1-dimethylallyl fragment is formed within 2 ns of excitation, whereas the methyl radical and N2 are formed through decay of reaction intermediate having a lifetime of 12 +/- 2 ns.These findings mark the first direct demonstration of a stepwise homolysis mechanism for an azoalkane.
Contact:86-25-58619180
Address:Nanjing High-Tech Zone 10 Xinghuo Road Pukou District Nanjing, Jiangsu 210061 The People's Republic of China
Contact:+86-25-52346955
Address:199,JIANYE ROAD,NANJING,CHINA
Tianjin Jingye Fine Chemicals Co., Ltd.
Contact:+86-15722078107; +86-22-26911407
Address:Bohua Fine Chemicals Base of Petrochemical Industry Park, Nanhuan Road, Dagang District, Tianjin, 300271, P. R. China
Jining tiansheng chemical co.,ltd.
Contact:+86-537-5158722
Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA
Jiangyin Tenghua Import&Export Co.,Ltd.
Contact:+86-510-86263875
Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
Doi:10.1021/j100370a040
(1990)Doi:10.1016/j.bmc.2020.115495
(2020)Doi:10.1039/c39810000981
(1981)Doi:10.1021/jo01375a016
(1954)Doi:10.1021/j100349a009
(1989)Doi:10.1246/bcsj.71.397
(1998)
