Journal of Physical Chemistry p. 4707 - 4710 (1989)
Update date:2022-08-31
Topics:
Tyndall, G. S.
Ravishankara, A. R.
Laser-induced fluorescence was used to detect CH3S radicals in the laser flash photolysis of CH3SH-O3-H2O-He(SF6) mixtures.Evidence was found for a reaction between CH3S and O3, with a rate coefficient (4.1+/-2.0)x10E-12 cm3 molecule-1s-1.The yield of CH3S from the reaction OH + CH3SH was determined to be 1.1+/-0.2.Our results suggest that the CH3S + O3 reaction could be the major sink for CH3S in the atmosphere.
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