INTRAMOLECULAR ELECTRON TRANSFER AT METAL SURFACES. 3. INFLUENCE OF BOND CONJUGATION ON REDUCTION KINETICS OF COBALT(III) ANCHORED TO ELECTRODES VIA THIOPHENECARBOXYLATE LIGANDS.

Article abstract of DOI:10.1021/ja00317a011

Unimolecular rate constants, k//e//t, are reported for the one-electron electroreduction of pentaamminecobalt(III) anchored to mercury, gold, or copper electrodes via various thiophenecarboxylate ligands where the thiophene sulfur acts as the surface bind