DIMETHYLDIOXIRANE CONVERSION OF PHOSHINE SULFIDES AND PHOSPHOROTHIOATES INTO THEIR CORRESPONDING OXYGEN ANALOGUES

DOI: 10.1016/S0040-4039(00)89065-6

Source and publish data:

Tetrahedron Letters p. 3359 - 3362 (1990)

Update date:2022-08-11

Topics:

Authors:

Sanchez-Baeza, Francisco

Durand, Gael

Barcelo, Damia

Messeguer, Angel

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Article abstract of DOI:10.1016/S0040-4039(00)89065-6

Tributyl and triphenyl sulfides react with dimethyldioxirane to give the corresponding oxides in quantitative yields.The procedure has also been used for the rapid and clean conversion of several insecticidal phosphorothioates into their respective triester phosphates, which are compounds of interest as standards for toxicological and environmental studies.

Full text of DOI:10.1016/S0040-4039(00)89065-6

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