Transactions of the Faraday Society p. 898 - 900 (1970)
Update date:2022-08-11
Topics:
LEYLAND LM
MAJER JR
ROBB JC
The difference in the energies of activation, combined with known thermochemical data gives a value for the heat of formation of the CF//2Cl. radical of 64. 3 kcal and a value for D(CH//2Cl-H) of 103. 8 kcal. Combination of this value with the measured appearance potential of (CF//2Cl) cation from CF//2Cl//2 gives a value for the ionization potential of the CF//2Cl. radical of 9. 1 ev. Bond- dissociation energies in several molecules containing the CF//2Cl. radicals have been determined from the appropriate appearance potentials of (CF//2Cl) cation.
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