Tetrahedron Letters p. 2661 - 2664 (1987)
Update date:2022-08-30
Topics:
Anderson, Derek W.
Black, Robin M.
Leigh, David A.
Stoddart, Fraser J.
Williams, Nancy E.
T-2 Toxin (5) and neosolaniol (6) are readily converted into anguidine (1) by a procedure where deoxygenation at the C-8 position is achieved, after conversion of the 3-TBDMS ether 7 of neosolaniol (6) to the β-bromide 11 for reduction to the anguidine precursor 12.
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Doi:10.1021/ja00995a074
(1967)Doi:10.1039/c2ob26955d
(2013)Doi:10.1021/jo01037a505
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(1938)Doi:10.1021/ac00238a042
(1982)Doi:10.1002/chem.201403945
(2014)
