Bioorganic and Medicinal Chemistry Letters p. 1047 - 1048 (1999)
Update date:2022-08-11
Topics:
Iori
Bernardi
Gueyrard
Rollin
Palmieri
A new semi-synthetic way to produce glucoraphanin (2), the bio-precursor of the potential anticarcinogen sulforaphane (3), has been developed. Starting from glucoerucin (1), isolated from ripe seeds of Eruca sativa, glucoraphanin was obtained through chemoselective oxidation. Controlled myrosinase-catalysed hydrolysis of this precursor quantitatively afforded sulforaphane.
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