Asymmetric cleavage of chiral α,β-ethylenic acetals by organolithium reagents

DOI: 10.1016/S0957-4166(96)00438-7

Source and publish data:

Tetrahedron Asymmetry p. 3343 - 3346 (1996)

Update date:2022-08-17

Topics:

Authors:

Alexakis, Alexandre

Mhamdi, Farida

Lagasse, Franz

Mangeney, Pierre

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Article abstract of DOI:10.1016/S0957-4166(96)00438-7

,β-Ethylenic chiral acetals react regio- and stereoselectively with organolithium reagents. The obtained enol ether may be hydrolyzed into a chiral β-disubstituted aldehyde.

Full text of DOI:10.1016/S0957-4166(96)00438-7

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