Russian Chemical Bulletin p. 431 - 437 (2000)
Update date:2022-08-11
Topics:
Vasilieva
Kleshcheva
Gromova
Rebrov
Filatova
Krut'ko
Timofeeva
Topchiev
The first synthesis of high-molecular-weight poly( N,N-diallyl-N-methylamine) by thermal (at 30 and 50 °C) and photoinduced (at 21 °C) radical polymerization of N,N-diallyl-N-methylamine (DAMA) in aqueous solution in the presence of an equimolar amount of trifluoroacetic acid (TFA) and by polymerization of the newly synthesized equimolar DAMA · TFA salt is reported. Data of 1H NMR spectroscopy indicate that the molecules of the monomer under chosen conditions are in the protonated form. This leads to a decrease in the contribution of the reaction of degradative chain transfer to the monomer and its transformation into effective chain transfer to the monomer. A bimolecular chain termination mechanism was established and the possibility of controlling the polymerization rate and the molecular weight of the polymer was demonstrated.
View MoreShanghai Chemchallenger Biotech Co., Ltd.
Contact:0086-21-68110815
Address:Room 2056, Building 1, No. 1065, Jiaxin Road Shanghai China (Mainland) 201800
Huangshan Honghui Pharm Technology Co., Ltd.
website:http://www.honghuichem.com
Contact:18855958372
Address:Qingshan Wan No.1,Nanyuan Kou,SheXian Huangshan City,Anhui Province
Chemtrade International ( China )
Contact:+86-532-86893005
Address:Rm 2-501, Huaxia Zonghe Building, No. 410 JInggangshan Road, Huangdao
ABA Chemicals (Shanghai) Limited
Contact:021- 5115 9199-232
Address:Suite 18D, #201 Ningxia Road,
Contact:86-25-58619180
Address:Nanjing High-Tech Zone 10 Xinghuo Road Pukou District Nanjing, Jiangsu 210061 The People's Republic of China
Doi:10.1002/jhet.3920
(2020)Doi:10.1039/j19710001547
(1971)Doi:10.1246/bcsj.68.997
(1995)Doi:10.1016/j.apcata.2012.05.009
(2012)Doi:10.1002/kin.21063
(2017)Doi:10.1016/j.bmc.2017.02.066
(2017)