
Angewandte Chemie - International Edition in English p. 1005 - 1006 (1996)
Update date:2022-08-11
Topics:
Breunig
Denker
Lork
Only stable in the crystal, the title compound 1 contains the first example of a polynuclear organoantimony cation. Interionic Sb···Sb and Sb···Br contacts are observed in 1, and reversible dissociation of 1 in solution gives the starting materials Mc2ShBr and Mc4Sb2. These components exchange Mc2Sb groups in the formation of 1.
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Doi:10.1007/BF00910116
()Doi:10.1007/s101070100240
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