Bulletin of the Chemical Society of Japan p. 1662 - 1666 (1984)
Update date:2022-08-16
Topics:
Rokicki
Kuran
A study has been carried out on the reaction of alkali metal carbonates with epihalohydrins in the presence of cation complexing agents e. g. crown ethers. 3-Glycidyloxypropylene carbonate was found to be formed as the main product of the reaction of epichlorohydrin with potassium carbonate promoted by 18-crown-6. The effect of various epihalohydrins and alkali metal carbonates on the reaction course was examined. It was found that the reaction of potassium hydrogencarbonate with epichlorohydrin gives 4-hydroxymethyl-1,3-dioxolan-2-one. When the reaction of epihalohydrins with potassium carbonates was carried out in the atmosphere of carbon dioxide the products contained linear carbonate linkage apart from cyclic one.
View More
Chengdu D-Innovation Pharmaceutical Co., Ltd
Contact:86-28-85105536
Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone
QINGDAO TAOSIGN INTERNATIONAL TRADE CO.,LIMITED
Contact:+86-0532-82683616
Address:RM1402, Doublestar Seacoase 7#, No. 5 Guizhou Road, Qingdao, Shandong, China
Wuxi Zuping Food Science And Technology Co.,LTD.
Contact:+86-510-87210822
Address:Guanlin town
Changsha Huajing Powdery Material Technological Co., Ltd.
Contact:86-731-88879686
Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China
SHANXI JINJIN CHEMICAL INDUSTRIAL CO.,LTD
website:http://www.jinjingroup.com
Contact:86-574-13989382828
Address:Economic And Technological Development Zone,Hejin?City,Shanxi Province?,China
Doi:10.1016/j.bmcl.2015.05.018
(2015)Doi:10.1248/cpb.45.421
(1997)Doi:10.1248/yakushi1947.87.8_1012
(1967)Doi:10.1039/b502197a
(2005)Doi:10.1021/ol026068w
(2002)Doi:10.1016/j.tetlet.2007.02.094
(2007)
