Palladium-catalysed Allylic Sulphinate-Sulphone Rearrangements; Asymmetric Induction in the Palladium-catalysed Transfer of Chiral Sulphinates to Sulphones

DOI: 10.1039/c39840000303

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Journal of the Chemical Society. Chemical communications p. 303 - 305 (1984)

Update date:2022-08-17

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Authors:

Hiroi, Kunio

Kitayama, Ryuichi

Sato, Shuko

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Article abstract of DOI:10.1039/c39840000303

The rearrangement of allylic sulphinates to sulphones is facilitated by palladium catalysis, treatment of the chiral trans- and cis-allyl sulphinates (S)-(-)-(1a), -(1c), and -(1e), and (S)-(-)-(1b) and -(1d) with a catalytic amount of the palladium catal

Full text of DOI:10.1039/c39840000303

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