The effect of collisions in the multiphoton decomposition of 1-bromo-2-fluoroethane

Article abstract of DOI:10.1063/1.459096

The multiphoton decomposition (MPD) of 1-bromo 2-fluoroethane, CH2BrCH2F, with a pulsed CO2 infrared laser is reported.The decompsition study was done at constant fluence and at pressures up to 2 kPa.Empirical representations of the pressure dependence of the MPD are reported.A collision-dependent reaction scheme is presented to explain the pressure dependence of the up-pumping through the vibrational manifold.

Full text of DOI:10.1063/1.459096

The effect of collisions in the multiphoton decomposition of 1bromo 2fluoroethane
Glenn A. McRae, D. K. Evans, and J. W. Goodale
Citation: The Journal of Chemical Physics 93, 1689 (1990); doi: 10.1063/1.459096
View online: http://dx.doi.org/10.1063/1.459096
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/93/3?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
137.189.170.231 On: Fri, 19 Dec 2014 08:35:34

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
137.189.170.231 On: Fri, 19 Dec 2014 08:35:34

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
137.189.170.231 On: Fri, 19 Dec 2014 08:35:34

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
137.189.170.231 On: Fri, 19 Dec 2014 08:35:34

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
137.189.170.231 On: Fri, 19 Dec 2014 08:35:34

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
137.189.170.231 On: Fri, 19 Dec 2014 08:35:34