A general access to α,ss-acetylenic thiocarbonyl compounds

Article abstract of DOI:10.1080/10426509908546451

Reaction of several α,β-acetylenic carbonyl compounds with bis(trimethyl)silylsulfide/TfOTMS affords the first example for the synthesis of thioketones, thioacylsilane and thioaldehyde in the acetylenic series.

Full text of DOI:10.1080/10426509908546451

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Phosphorus, Sulfur, and
Silicon and the Related
Elements
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A General Access to α,β-
Acetylenic Thiocarbonyl
Compounds
Alessandro Degl'innocenti , Antonella
Capperucci , Patrizia Scafato , Tommaso
Mecca , Alessandro Mordini & Gianna
Reginato
a
Centro CNR Composti Eterociclici,
Dipartimento di Chimica Organica, via Gino
Capponi , 9–1–50121 Firenze, (Italy)
b
Centro CNR Composti Eterociclici,
Dipartimento di Chimica Organica, via Gino
Capponi , 9–1–50121 Firenze, (Italy)
c
Dipartimento di Chimica, via N. Sauro , 85
–
1 85100 Potenza, (Italy)
d
Dipartimento di Chimica, via N. Sauro , 85
1 85100 Potenza, (Italy)
–
e
Centro CNR Composti Eterociclici,
Dipartimento di Chimica Organica, via Gino
Capponi , 9–1–50121 Firenze, (Italy)
f
Centro CNR Composti Eterociclici,
Dipartimento di Chimica Organica, via Gino
Capponi , 9–1–50121 Firenze, (Italy)
Published online: 17 Mar 2008.

To cite this article: Alessandro Degl'innocenti , Antonella Capperucci ,
Patrizia Scafato , Tommaso Mecca , Alessandro Mordini & Gianna Reginato
(1999) A General Access to α,β-Acetylenic Thiocarbonyl Compounds,
Phosphorus, Sulfur, and Silicon and the Related Elements, 153:1, 321-322,
DOI: 10.1080/10426509908546451
To link to this article: http://dx.doi.org/10.1080/10426509908546451
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