Journal of the Chemical Society. Chemical communications p. 388 - 389 (1980)
Update date:2022-08-11
Topics:
Scott, A. Ian
Hansen, John B.
Chung, Sung-Kee
Mechanistic probes of a model system for the coenzyme-B12-dependent methylmalonyl-CoA mutase reaction have suggested (i) that the C-Co bond in the alkylcobalamin intermediate is capable of both carbanionic and homolytic cleavage, and (ii) that the skeletal rearrangement most probably takes place at the radical stage.
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