SYNTHESE DE PERFLUORO-nHEXYL-2 ETHANOL C6F13C2H4OH PAR REDUCTION ELECTROCHIMIQUE SUR FIBRES DE CARBONE DE PERFLUORO-nHEXYL-2 IODO-1 ETHANE C6H13C2H4I DANS LE SOLVANT N,N DIMETHYLFORMAMIDE

DOI: 10.1016/S0022-1139(00)82780-3

Source and publish data:

Journal of Fluorine Chemistry p. 245 - 260 (1988)

Update date:2022-08-16

Topics:

Authors:

Benefice-Malouet, S.

Blancou, H.

Calas, P.

Commeyras, A.

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Article abstract of DOI:10.1016/S0022-1139(00)82780-3

Electrochemical reduction of 2-perfluoro-nhexyl-1-iodo-ethane at a carbon fibre cathode, in N,N-dimethylformamide as solvent, leads to the perfluoro-nhexyl-2-ethanol with perfluoro-nhexyl-2-ethylene as the major by-product.A mechanism is proposed on the basis of results obtained from macro-scale electrolysis and a study of Linear Sweep Voltammetry.

Full text of DOI:10.1016/S0022-1139(00)82780-3

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