
Bulletin of the Chemical Society of Japan p. 1389 - 1391 (1991)
Update date:2022-08-10
Topics:
Watanabe, Osamu
Suzuki, Eiichi
Watari, Fumio
Argon-matrix isolated thietane at 10 K decomposed by irradiation (λ > 290 nm) to form ethylene and thioformaldehyde.The photolysis of thietane under these conditions has been shown to be a clean source of thioformaldehyde.The CH2S and CD2S molecules generated this way are indefinitely stable and their infrared spectra could be recorded.
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