Ring-Expansion Reactions Catalyzed by Hydrophobic Vitamin B12 in Synthetic Bilayer Membrane

DOI: 10.1246/cl.1988.621

Source and publish data:

Chemistry Letters p. 621 - 624 (1988)

Update date:2022-08-11

Topics:

Authors:

Murakami, Yukito

Hisaeda, Yoshio

Ohno, Teruhisa

Matsuda, Yoshihisa

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Article abstract of DOI:10.1246/cl.1988.621

Heptapropyl cobyrinate perchlorate catalyzed the ring-expansion reactions, which convert 2-methyl-1,3-cyclopentanedion and 3-methyl-2-pyrrolidinone into 1,4-cyclohexanedione and 2-piperidinone, respectively, in single-compartment bilayer vesicles.

Full text of DOI:10.1246/cl.1988.621

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