Journal of Organic Chemistry p. 3407 - 3410 (1993)
Update date:2022-08-30
Topics:
Pavlik, James W.
Pandit, Chennagiri R.
Samuel, Christopher J.
Day, A. Colin
Methylisothiazoles undergo phototransition in neutral solution to methylthiazoles by a single permutation process.Methylisothiazole -> methylisothiazole transpositions, previously reported to occur, were not detected in these reactions.In trifluoroacetic acid solvent, protonated methylisothiazoles and methylthiazoles phototranspose by P4 and P5 permutation pathways, respectively, resulting in a unique phototransposition cycle.
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