Journal of Organometallic Chemistry p. 21 - 30 (1981)
Update date:2022-08-11
Topics:
Cloutour, Catherine
Debaig-Valade, Caroline
Pommier, Jean-Claude
Dabosi, Guy
Martineau, Monique
Irradiation of dihydroxystannyltetraphenylporphyrin with visible light in the presence of SnCl2, 2H2O in pyridine leads by photoreduction to dihydroxystannyltetraphenylisobacteriochlorin.The synthesis of dihydroxystannyltetraphenylchlorine by insertion of SnCl2 in tetraphenylchlorine is described.The results of a comparative electrochemical study of these different compounds are reported and show a net increase of -E1/2red for the isobacteriochlorine derivative.
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Doi:10.1021/ja00346a083
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