FONTIONNALISATION DES IODURES DE F-ALKYL-2 ETHANE PAR CATALYSE PAR TRANSFERT DE PHASE: IMPORTANCE DE CETTE TECHNIQUE EN SERIE F-ALKYLEE

Article abstract of DOI:10.1016/S0022-1139(00)83967-6

F-alkyl-2 ethane iodides are very important starting materials in the field of organic chemistry.Their reactivity in homogeneous medium shows some drawbacks: reactions are uncomplete and resulting compounds are not pure.We resolved these problems using phase transfer catalysis and obtained outstanding results.F-alkyl-2 ethane iodides are strongly hydrophobic; so organic solvents are not necessary (water was used) and moreover the emulsions promoted during the reaction are not stable.