THERMAL REARRANGEMENT OF DIENOLESTERS. SEQUENTIAL SIGMATROPIC REARRANGEMENT AND INTERMOLECULAR DIELS-ALDER CYCLOADDITION OF 1-METHYLENE-2-METHYL-2-PROPENYL HEX-5-ENOATE

DOI: 10.1016/S0040-4039(00)87148-8

Source and publish data:

Tetrahedron Letters p. 1523 - 1526 (1982)

Update date:2022-08-10

Topics:

Authors:

Shea, K. J.

Wada, E.

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Article abstract of DOI:10.1016/S0040-4039(00)87148-8

The high temperature thermal rearrangement of the title dienol ester is reported.Its reactions entail a <1.3> acyl shift followed by intramolecular Diels-Alder cycloaddition of the resulting β-diketone.

Full text of DOI:10.1016/S0040-4039(00)87148-8

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