Tetrahedron Letters p. 661 - 664 (1985)
Update date:2022-08-29
Topics:
Takeuchi, Ken'ichi
Miyazaki, Tadakazu
Kitagawa, Itsuko
Okamoto, Kunio
The reaction of 1-adamantyl triflate (1) with carbon monoxide and adamantane catalyzed by triflic acid affords 3-hydroxy-4-homoadamantyl 1-adamantanecarboxylate (2) as a major product, which is easily converted to 3,4-homoadamantanediol (5) - a promising starting material for 3,4-bifunctional homoadamantane derivatives.
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