Tetrahedron Letters p. 359 - 362 (1985)
Update date:2022-08-11
Topics:
Dunkin, Ian R.
Donnelly, Thomas
Lockhart, Thomas S.
Photolysis of 2,6-dimethylphenyl azide on N2 matrices at 12K gives 2,6-dimethylphenylnitrene; in presence of CO, the nitrene forms the corresponding isocyanate, while on shorter wavelength irradiation, it undergoes an inefficient rearrangement to an azacycloheptatetraene.
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