Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1462 - 1465 (1992)
Update date:2022-08-16
Topics:
Es'kova, L. A.
Erushnikova, L. P.
Afonin, A. V.
Domnina, E. S.
It was found vinylpyrazoles react with thiols both according to ionic and according to free-radical mechanisms, with the formation of products of α- and β-addition.Radical thiylation of 1-vinylpyrazoles is a convenient method of synthesis of pyrazoles with sulfur-containing substituents. Keywords: Vinylpyrazoles, vinylimidazole, alkanethiols, α-, β-addition, free-radical ionic initiation, photoinitiation, disproportionation.
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