Russian Chemical Bulletin p. 619 - 623 (1994)
Update date:2022-08-17
Topics:
Eremenko, L. T.
Romanova, L. B.
Ivanova, M. E.
Eremenko, I. L.
Nefedov, S. E.
Struchkov, Yu. T.
An effective methods of esterification of 1,4-cubanedicarboxylic acid with alkylsulfuric acids is proposed.The derivatives of alkanols with substantially different pKa values are obtained in high yields.Molecular structures of the esters obtained are confirmed by various methods.The X-ray study showed a remarcable effect of the nature of an alkyl radical on the geometry of the cubane core. - Key words: 1,4-cubanedicarboxylic acid, esterification, alkylsulfuric acids, X-ray method.
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