
Bulletin of the Chemical Society of Japan p. 3814 - 3816 (1987)
Update date:2022-08-17
Topics:
Yamamoto, Jiro
Tsuboi, Takashi
Sumi, Yasunori
Oda, Noriyasu
Fukuyama, Keiichi
A treatment of 3-chloro-NNO-4'-methylazoxybenzene (1β) with CrO3 in acetic acid gave 3-chloro-ONN-4'-methylazoxybenzene (1α) in good yield, whereas 4-methoxy-ONN-4'-methylazoxybenzene (2α) isomerized partially to 4-methoxy-NNO-4'-methylazoxybenzene (2β) under the same conditions.The structures of 1α and 2α have been determined by X-ray analysis.
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