Preparations and Structures of 3-Chloro-ONN-4'-methylazoxybenzene and 4-Methoxy-ONN-4'-methylazoxybenzene

DOI: 10.1246/bcsj.60.3814

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3814 - 3816 (1987)

Update date:2022-08-17

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Authors:

Yamamoto, Jiro

Tsuboi, Takashi

Sumi, Yasunori

Oda, Noriyasu

Fukuyama, Keiichi

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Article abstract of DOI:10.1246/bcsj.60.3814

A treatment of 3-chloro-NNO-4'-methylazoxybenzene (1β) with CrO3 in acetic acid gave 3-chloro-ONN-4'-methylazoxybenzene (1α) in good yield, whereas 4-methoxy-ONN-4'-methylazoxybenzene (2α) isomerized partially to 4-methoxy-NNO-4'-methylazoxybenzene (2β) under the same conditions.The structures of 1α and 2α have been determined by X-ray analysis.

Full text of DOI:10.1246/bcsj.60.3814

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