Tetrahedron Letters p. 5041 - 5044 (1985)
Update date:2022-08-28
Topics:
Boucher, Jean-Luc
Stella, Lucien
We show that the cycloaddition of α-methylthioacrylonitrile to cyclohexadiene is faster than that of acrylonitrile.This indicates that the captodative substitution exerts an accelerating effect on the Diels-Alder reaction despite the larger steric bulk of the methylthio group compared to hydrogen.
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