Tetrahedron Letters p. 4895 - 4898 (1997)
Update date:2022-08-11
Topics:
Malkov, Andrei V.
Baxendale, Ian
Mansfield, Darren J.
Kocovsky, Pavel
The new Mo(II) triflate complex 5 has been found to catalyze the C-C bond forming allylic substitution with silyl enol ethers derived from β-dicarbonyls (e.g., 6 + 12 → 14) and from simple ketones (e.g., 6 + 13 → 16) as nucleophiles.
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