
Journal of Fluorine Chemistry p. 189 - 197 (1997)
Update date:2022-08-17
Topics:
Farooq, Omar
Alkali metal hexafluorophosphates were used to effect nucleophilic fluorination of a few selected alkoxysilanes both in the presence and absence of polar solvents. Near-quantitative yields of fluorinated silanes were obtained using both alkoxy-equivalent of the complex salt and fluoride equivalents of alkoxysilanes. Some of the intermediate fluorosilanes and fluorophosphorus compounds were identified and the mechanism of fluorination is proposed.
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