Tetrahedron Letters p. 3849 - 3850 (1991)
Update date:2022-08-17
Topics:
Costantini, C.
Crescenzi, O.
Prota, G.
Kinetic and isotopic labelling studies provide for the first time evidence that at physiological pH the rearrangement of dopachrome (1) to 5,6-dihydroxyindole (2) involves abstraction of the proton at position 3 and formation of the intermediate quinone-methide 4.
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Doi:10.1002/chem.202003937
(2021)Doi:10.1016/S0040-4039(00)00254-9
(2000)Doi:10.1246/bcsj.65.3423
(1992)Doi:10.1016/S0040-4039(01)91943-4
(1974)Doi:10.1055/s-2005-861797
(2005)Doi:10.1016/j.molstruc.2020.129806
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