Tetrahedron Letters p. 3849 - 3850 (1991)
Update date:2022-08-17
Topics:
Costantini, C.
Crescenzi, O.
Prota, G.
Kinetic and isotopic labelling studies provide for the first time evidence that at physiological pH the rearrangement of dopachrome (1) to 5,6-dihydroxyindole (2) involves abstraction of the proton at position 3 and formation of the intermediate quinone-methide 4.
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Doi:10.1002/chem.202003937
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