Synthesis p. 654 - 655 (1986)
Update date:2022-08-17
Topics:
Barluenga, Jose
Alvarez, Flora
Concellon, Jose M.
Yus, Miguel
The reaction of the lithium enolate of ethyl acetate with various α-chlorocarbonyl compounds followed by in situ reduction with lithium aluminium hydride or deuteride and then lithiation with lithium powder leads, after hydrolysis, to homoallylic alcohols in a regioselective manner.
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