REACTIONS OF PENTAFLUOROSULFANYLIMINODIHALOSULFANES, SF5N=SX2, WITH NUCLEOPHILES. PREPARATION AND CHARACTERIZATION OF PENTAFLUOROSULFANYLSULFINYLAMINE, SF5N=S=O

Article abstract of DOI:10.1016/S0022-1139(00)82671-8

Reactions of SF5N=SF2 with sodium alkoxides and aryloxides have produced both the mono- and disubstituted derivatives SF5N=S(F)OR and SF5N=S(OR)2, where R=CH3, CH2CH=CH2, C6H5, p-C6H4NO2, p-C6H4Br, p-C6H4CN.The reaction of SF5N=SCl2 with AgNCO produced SF