Total synthesis of (-)-austalide B. A generic solution to elaboration of the Pyran/p-Cresol/Butenolide triad

DOI: 10.1021/ja00104a012

Source and publish data:

Journal of the American Chemical Society p. 11323 - 11334 (1994)

Update date:2022-08-22

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Authors:

Paquette, Leo A.

Wang, Ting-Zhong

Sivik, Matthew R.

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Article abstract of DOI:10.1021/ja00104a012

The toxic meroterpenoid (-)-austalide B has been prepared in its natural form by chemical modification of the readily available optically active enedione 11. Following stereocontrolled Robinson annulation to give 13 and fully regiocontrolled gem-dimethyla

Full text of DOI:10.1021/ja00104a012

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