THE INTERMOLECULAR BENZYNE CYCLOADDITION APPROACH TO DEHYDRONORAPORPHINES AND OXOAPORPHINES. TOTAL SYNTHESIS OF PO-3

DOI: 10.1016/S0040-4039(00)88958-3

Source and publish data:

Tetrahedron Letters p. 4559 - 4560 (1985)

Update date:2022-08-22

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Authors:

Saa, Carlos

Guitian, Enrique

Castedo, Luis

Saa, Jose M.

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Article abstract of DOI:10.1016/S0040-4039(00)88958-3

The synthesis of dehydronoraporphines and oxoaporphines has been achieved by means of the convergent and highly regioselective intermolecular benzyne cycloaddition approach.The first total synthesis of the quaternary oxoaporphine PO-3 is described.

Full text of DOI:10.1016/S0040-4039(00)88958-3

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