Chemistry Letters p. 1309 - 1312 (1992)
Update date:2022-08-10
Topics:
Kojima, Masanobu
Ojima, Yuichi
Nakashima, Nobuaki
Izawa, Yasukazu
Akano, Toru
Yamanaka, Chiyoe
Electronically excited oxygen atom O(1D), generated by photolysis of CO2 with a 158 nm (F2) laser, react with CH4, CF3H, and CF3CH3 to give corresponding vibrationally excited alcohols (ROH*) by insertion into the C-H bonds, which collapse to vibrationally relaxed alcohols or alkyl and hydroxy radical pairs depending on the stability and lifetime of ROH*.
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