
Journal of the American Chemical Society p. 4958 - 4959 (1980)
Update date:2022-08-24
Topics:
Kumar, Ramesh C.
Shreeve, Jean'ne M.
The new compounds F-ethylamine, C2F5NH2, and F-ethylimine, CF3CF=NH, are readily prepared by the reaction of N,N-dichloro-F-ethylamine with trimethylsilane at -45 or -25 deg C, respectively.Both compounds are subject to dehydrofluorination.Thus, CF3CF=NH may be obtained by the loss of a single HF molecule from CF3CF2NH2 at -25 deg C.CF3CF2NH2 will react with SF4 to form CF3CF2N=SF2.Similarly, CF3CF=NH forms CF3CF=NCl with ClF in the presence of CsF.
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