High oxygen-binding affinity of poly(4-vinylimidazole-co-octylmethacrylate)-cobaltporphyrin complex: effect of hydrogen-bond at the imidazole residue

Article abstract of DOI:10.1080/10587250008038273

The oxygen-binding affinity of the cobalt-picketfence-porphyrin (CoP) ligated with imidazole was enhanced in the presence of an additive which forms a hydrogen-bond with the ligated imidazole. The CoP complex with poly(4(5)-vinylimidazole-co-octylmethacrylate) rapidly and reversibly bound oxygen and showed very high oxygen-binding affinity: The oxygen transport in the CoP-polymer membrane was efficiently facilitated.

Full text of DOI:10.1080/10587250008038273

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Molecular Crystals and
Liquid Crystals Science
and Technology. Section A.
Molecular Crystals and Liquid
Crystals
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High Oxygen-Binding Affinity
of Poly(4-Vinylimidazole-
co-octylmethacrylate)-
Cobaltporphyrin Complex:
Effect of Hydrogen-Bond at the
Imidazole Residue
Hiroyuki Nishide a , Aiko Kato a & Eishun Tsuchida a
a Department of Polymer Chemistry , Waseda
University , Tokyo, 169-8555, Japan
Published online: 24 Sep 2006.
To cite this article: Hiroyuki Nishide , Aiko Kato & Eishun Tsuchida (2000)
High Oxygen-Binding Affinity of Poly(4-Vinylimidazole-co-octylmethacrylate)-
Cobaltporphyrin Complex: Effect of Hydrogen-Bond at the Imidazole Residue,
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular
Crystals and Liquid Crystals, 342:1, 249-254, DOI: 10.1080/10587250008038273
To link to this article: http://dx.doi.org/10.1080/10587250008038273
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