A new method for the reductive cleavage of Se-Se bond by titanocene dichloride isobutylmagnesium bromide and its application in synthesis of selenoester

Article abstract of DOI:10.1080/00397919708007304

The reduction of diaryldiselenides by Cp₂TiCl₂/2i-BuMgBr/THF led to arylselenium complex of titanocene (Cp₂TiSeAr). This species reacts smoothly with acidic anhydrides to give selenoesters.

Full text of DOI:10.1080/00397919708007304

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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A New Method for the
Reductive Cleavage of Se-Se
Bond by Titanocene Dichloride
Isobutylmagnesium Bromide
System and Its Application in
Synthesis of Selenoester
Xin-Hua Xu a & Xian Huang a
a Department of Chemistry , Hangzhou University
Hangzhou , Zhejiang, 310028, P. R. China
Published online: 22 Aug 2006.
To cite this article: Xin-Hua Xu & Xian Huang (1997) A New Method for the Reductive
Cleavage of Se-Se Bond by Titanocene Dichloride Isobutylmagnesium Bromide System
and Its Application in Synthesis of Selenoester, Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry, 27:21,
3797-3801, DOI: 10.1080/00397919708007304
To link to this article: http://dx.doi.org/10.1080/00397919708007304
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