Synthesis of heteronuclear di- and tri-metal μ-carbyne compounds from the thiocarbyne (CO)2WCSMe

DOI: 10.1016/0022-328X(89)85008-9

Source and publish data:

Journal of Organometallic Chemistry p. 81 - 90 (1989)

Update date:2022-08-11

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Authors:

Doyle, Ruth Ann

Angelici, Robert J.

Gordon F.

Stone, A.

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Article abstract of DOI:10.1016/0022-328X(89)85008-9

The compound (CO)2WC-SMe (1) reacts with two equivalents of (In)Rh(CO)2, where In = η⁵-indenyl, C9H7, in refluxing THF to give the brown-black crystalline μ3-carbyne <(In)2(μ-CO)Rh2(μ3-CSMe)W(CO)2> (2) containing a Rh2W triang

Full text of DOI:10.1016/0022-328X(89)85008-9

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