Bulletin of the Chemical Society of Japan p. 657 - 660 (1998)
Update date:2022-08-29
Topics:
Kimura, Keiichi
Tsujimura, Yutaka
Yokohama, Masaaki
Maeda, Takumi
An oligo(dimethylsiloxane) carrying ionophorous calix[4]arene moieties at the side chain was synthesized as a Na+ neutral carrier for highly durable silicone-ruhher membranes of ion-selective electrodes by reacting calix[4]arene tetraallyl ester with an oligo(methylsiloxane). This medium-molecular-weight calix[4]arene ionophore alleviated the drawback of chemically-modified calixarene-based silicone-rubber membranes, such as a high membrane impedance and a slow electrode response.
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