Journal of Catalysis p. 26 - 32 (1995)
Update date:2022-08-29
Topics:
Garin, F.
Seyfried, L.
Girard, P.
Maire, G.
Abdulsamad, A.
Sommer, J.
The reactions of n-butane and isobutane have been studied in a flow system in the presence of hydrogen at 250 deg C using sulfuric acid treated zirconia as catalyst.The conversion of the butanes occurs with high selectivity in isomerization.The branched isomer reacts much faster than the linear one.The use of 13C labelled starting material and analysis of the isotope distribution in the products show that the rearrangement is of intramolecular nature in accord with the superacidic properties of the catalyst.
View More
Weihao Chemtech (ChangZhou) Co., Ltd.(expird)
Contact:051989185693
Address:NO 217 huangshan Rd ,Changzhou
Huangshi Shennong Chemical Technology Co., Ltd
Contact:+86-714-3072290
Address:Eastern industrial park , Tieshan district , Huangshi city ,Hubei province , China
Nanjing Fubang Chemical Co.,Ltd
Contact:+86-25-83179199
Address:5F,Tianzheng international plaza,No399 Zhongyang Road ,Nanjing China
Contact:+86-518-81061113
Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
Contact:86-27-84888681
Address:Wuhan economic & technology development zone
Doi:10.1016/S0040-4039(01)88387-8
(1969)Doi:10.1021/ol5019486
(2014)Doi:10.1021/jp970655v
(1997)Doi:10.1021/jo00192a019
(1984)Doi:10.1021/jo00318a036
(1981)Doi:10.1016/j.dyepig.2020.108270
(2020)
