Deoxy-nitrosugars. Synthesis of Methyl Shikimate and of Diethyl Phosphashikimate from D-Ribose

DOI: 10.1002/hlca.19840670621

Source and publish data:

Helvetica Chimica Acta p. 1562 - 1567 (1984)

Update date:2022-08-11

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Authors:

Mirza, Sohail

Vasella, Andrea

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Article abstract of DOI:10.1002/hlca.19840670621

The chain elongation of the deoxy-nitroribose 6 by a Michael addition to the vinylphosphonate 7 followed by a solvolysis gave the heptulosephosphonate 11 (87percent).From 11, the key intermediates 15 and 16 (77percent) were obtained by a highly diastereos

Full text of DOI:10.1002/hlca.19840670621

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