Journal of Fluorine Chemistry p. 299 - 308 (1985)
Update date:2022-08-29
Topics:
Lange, Horst
Naumann, Dieter
During the thermal decomposition of (CF3)2Cd and (CF3)2Zn complexes primarily difluorocarbene is eliminated.The formation of CF2 is unambiguously proved by matrix i.r. spectroscopy.Both (CF3)2Cd*D and (CF3)2Zn*D are excellent CF2 sources, which can easily be prepared and handled, and which undergo CF2 reactions even at low temperature.CF2 insertion was found during the reaction of (CF3)2Te with (CH3)2Cd via the intermediate formation of a CF3Cd compound to form CH3TeCF2CH3. (CF3)2Cd*glyme reacts with (CH3)3Si(OCOCF3) to CF3Cd(OCOCF3)*glyme; during this reaction CF2 is also eliminated.
View More
website:http://www.amadischem.com
Contact:86-571-89925085
Address:Watts Cosine.No.166.Xiangmao Road.
Contact:+86-577-65618087-605
Address:Room 402, Unit 4 Xinhu Bldg. Waitan Ruian City, Zhejiang China.
Contact:86-532-68629711 13780605697
Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Tianjin Pharmacn Medical Technology Co.,Ltd.
Contact:86-22-60122566ext.866(English),23359620
Address:Green Industrial Base, 6 Haitaifazhan Sixth Rd., Huayuan Industrial Area, Tianjin, 300384, China
Anyang Double Circle Auxiliary CO.,LTD
Contact:0086-134 6082 4403
Address:dongfeng road, anyang city, henan province,china
Doi:10.1071/CH18308
(2018)Doi:10.1021/ja01117a072
(1953)Doi:10.1039/c4ra17055e
(2015)Doi:10.1016/S0040-4039(01)87818-7
(1969)Doi:10.1021/jo026698b
(2003)Doi:10.1002/ejoc.200601126
(2007)
